Air-Sea Exchange of Biogenic Volatile Organic Compounds and the Impact on Aerosol Particle Size Distributions

Kim, MJ; Novak, GA; Zoerb, MC; Yang, M; Blomquist, BW; Huebert, BJ; Cappa, CD; Bertram, TH. 2017 Air-Sea Exchange of Biogenic Volatile Organic Compounds and the Impact on Aerosol Particle Size Distributions. Geophysical Research Letters. https://doi.org/10.1002/2017GL072975

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Abstract/Summary

We report simultaneous, underway eddy covariance measurements of the vertical flux of isoprene, total monoterpenes, and dimethyl sulfide (DMS) over the Northern Atlantic Ocean during fall. Mean isoprene and monoterpene sea-to-air vertical fluxes were significantly lower than mean DMS fluxes. While rare, intense monoterpene sea-to-air fluxes were observed, coincident with elevated monoterpene mixing ratios. A statistically significant correlation between isoprene vertical flux and short wave radiation was not observed, suggesting that photochemical processes in the surface microlayer did not enhance isoprene emissions in this study region. Calculations of secondary organic aerosol production rates (PSOA) for mean isoprene and monoterpene emission rates sampled here indicate that PSOA is on average <0.1 μg m−3 d−1. Despite modest PSOA, low particle number concentrations permit a sizable role for condensational growth of monoterpene oxidation products in altering particle size distributions and the concentration of cloud condensation nuclei during episodic monoterpene emission events from the ocean.

Item Type: Publication - Article
Additional Information. Not used in RCUK Gateway to Research.: An edited version of this paper was published by AGU. Copyright 2017 American Geophysical Union.
Subjects: Atmospheric Sciences
Marine Sciences
Divisions: Plymouth Marine Laboratory > Science Areas > Marine Biochemistry and Observations
Depositing User: Mingxi Yang
Date made live: 10 Mar 2018 11:58
Last Modified: 25 Apr 2020 09:58
URI: http://plymsea.ac.uk/id/eprint/7728

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